11 April 2009
Color film
The invention:Aphotographic medium used to take full-color pictures.
The people behind the invention:
Rudolf Fischer (1881-1957), a German chemist
H. Siegrist (1885-1959), a German chemist and Fischer’s
collaborator
Benno Homolka (1877-1949), a German chemist
The Process Begins
Around the turn of the twentieth century, Arthur-Louis Ducos du
Hauron, a French chemist and physicist, proposed a tripack (threelayer)
process of film development in which three color negatives
would be taken by means of superimposed films. This was a subtractive
process. (In the “additive method” of making color pictures,
the three colors are added in projection—that is, the colors are formed
by the mixture of colored light of the three primary hues. In the
“subtractive method,” the colors are produced by the superposition
of prints.) In Ducos du Hauron’s process, the blue-light negative
would be taken on the top film of the pack; a yellow filter below it
would transmit the yellow light, which would reach a green-sensitive
film and then fall upon the bottom of the pack, which would be sensitive
to red light. Tripacks of this type were unsatisfactory, however,
because the light became diffused in passing through the emulsion
layers, so the green and red negatives were not sharp.
To obtain the real advantage of a tripack, the three layers must
be coated one over the other so that the distance between the bluesensitive
and red-sensitive layers is a small fraction of a thousandth
of an inch. Tripacks of this type were suggested by the early pioneers
of color photography, who had the idea that the packs would
be separated into three layers for development and printing. The
manipulation of such systems proved to be very difficult in practice.
It was also suggested, however, that it might be possible to develop
such tripacks as a unit and then, by chemical treatment, convert the
silver images into dye images.Fischer’s Theory
One of the earliest subtractive tripack methods that seemed to
hold great promise was that suggested by Rudolf Fischer in 1912. He
proposed a tripack that would be made by coating three emulsions
on top of one another; the lowest one would be red-sensitive, the
middle one would be green-sensitive, and the top one would be bluesensitive.
Chemical substances called “couplers,” which would produce
dyes in the development process, would be incorporated into
the layers. In this method, the molecules of the developing agent, after
becoming oxidized by developing the silver image, would react
with the unoxidized form (the coupler) to produce the dye image.
The two types of developing agents described by Fischer are
paraminophenol and paraphenylenediamine (or their derivatives).
The five types of dye that Fischer discovered are formed when silver
images are developed by these two developing agents in the presence
of suitable couplers. The five classes of dye he used (indophenols,
indoanilines, indamines, indothiophenols, and azomethines)
were already known when Fischer did his work, but it was he who
discovered that the photographic latent image could be used to promote
their formulation from “coupler” and “developing agent.”
The indoaniline and azomethine types have been found to possess
the necessary properties, but the other three suffer from serious defects.
Because only p-phenylenediamine and its derivatives can be
used to form the indoaniline and azomethine dyes, it has become
the most widely used color developing agent.Impact
In the early 1920’s, Leopold Mannes and Leopold Godowsky
made a great advance beyond the Fischer process. Working on a
new process of color photography, they adopted coupler development,
but instead of putting couplers into the emulsion as Fischer
had, they introduced them during processing. Finally, in 1935, the
film was placed on the market under the name “Kodachrome,” a
name that had been used for an early two-color process.
The first use of the new Kodachrome process in 1935 was for 16-
millimeter film. Color motion pictures could be made by the Kodachrome process as easily as black-and-white pictures, because the
complex work involved (the color development of the film) was
done under precise technical control. The definition (quality of the
image) given by the process was soon sufficient to make it practical
for 8-millimeter pictures, and in 1936, Kodachrome film was introduced
in a 35-millimeter size for use in popular miniature cameras.
Soon thereafter, color processes were developed on a larger scale
and new color materials were rapidly introduced. In 1940, the Kodak
Research Laboratories worked out a modification of the Fischer
process in which the couplers were put into the emulsion layers.
These couplers are not dissolved in the gelatin layer itself, as the
Fischer couplers are, but are carried in small particles of an oily material
that dissolves the couplers, protects them from the gelatin,
and protects the silver bromide from any interaction with the couplers.
When development takes place, the oxidation product of the
developing agent penetrates into the organic particles and reacts
with the couplers so that the dyes are formed in small particles that
are dispersed throughout the layers. In one form of this material,
Ektachrome (originally intended for use in aerial photography), the
film is reversed to produce a color positive. It is first developed with
a black-and-white developer, then reexposed and developed with a
color developer that recombines with the couplers in each layer to
produce the appropriate dyes, all three of which are produced simultaneously
in one development.
In summary, although Fischer did not succeed in putting his theory
into practice, his work still forms the basis of most modern color
photographic systems. Not only did he demonstrate the general
principle of dye-coupling development, but the art is still mainly
confined to one of the two types of developing agent, and two of the
five types of dye, described by him.
COBOL computer language
The invention: The first user-friendly computer programming language,
COBOL was originally designed to solve ballistics problems.
The people behind the invention:
Grace Murray Hopper (1906-1992), an American
mathematician
Howard Hathaway Aiken (1900-1973), an American
mathematician
Plain Speaking
Grace Murray Hopper, a mathematician, was a faculty member
at Vassar College when World War II (1939-1945) began. She enlisted
in the Navy and in 1943 was assigned to the Bureau of Ordnance
Computation Project, where she worked on ballistics problems.
In 1944, the Navy began using one of the first electronic
computers, the Automatic Sequence Controlled Calculator (ASCC),
designed by an International Business Machines (IBM) Corporation
team of engineers headed by Howard Hathaway Aiken, to solve
ballistics problems. Hopper became the third programmer of the
ASCC.
Hopper’s interest in computer programming continued after
the war ended. By the early 1950’s, Hopper’s work with programming
languages had led to her development of FLOW-MATIC, the
first English-language data processing compiler. Hopper’s work
on FLOW-MATIC paved the way for her later work with COBOL
(Common Business Oriented Language).
Until Hopper developed FLOW-MATIC, digital computer programming
was all machine-specific and was written in machine
code. A program designed for one computer could not be used on
another. Every program was both machine-specific and problemspecific
in that the programmer would be told what problem the
machine was going to be asked and then would write a completely
new program for that specific problem in the machine code.Machine code was based on the programmer’s knowledge of the
physical characteristics of the computer as well as the requirements of
the problem to be solved; that is, the programmer had to know what
was happening within the machine as it worked through a series of calculations, which relays tripped when and in what order, and what
mathematical operations were necessary to solve the problem. Programming
was therefore a highly specialized skill requiring a unique
combination of linguistic, reasoning, engineering, and mathematical
abilities that not even all the mathematicians and electrical engineers
who designed and built the early computers possessed.
While every computer still operates in response to the programming,
or instructions, built into it, which are formatted in machine
code, modern computers can accept programs written in nonmachine
code—that is, in various automatic programming languages. They
are able to accept nonmachine code programs because specialized
programs now exist to translate those programs into the appropriate
machine code. These translating programs are known as “compilers,”
or “assemblers,” andFLOW-MATIC was the first such program.
Hopper developed FLOW-MATIC after realizing that it would
be necessary to eliminate unnecessary steps in programming to
make computers more efficient. FLOW-MATIC was based, in part,
on Hopper’s recognition that certain elements, or commands, were
common to many different programming applications. Hopper theorized
that it would not be necessary to write a lengthy series of instructions
in machine code to instruct a computer to begin a series of
operations; instead, she believed that it would be possible to develop
commands in an assembly language in such a way that a programmer
could write one command, such as the word add, that
would translate into a sequence of several commands in machine
code. Hopper’s successful development of a compiler to translate
programming languages into machine code thus meant that programming
became faster and easier. From assembly languages such
asFLOW-MATIC, it was a logical progression to the development of
high-level computer languages, such as FORTRAN (Formula Translation)
and COBOL.The Language of Business
Between 1955 (when FLOW-MATIC was introduced) and 1959, a
number of attempts at developing a specific business-oriented language
were made. IBM and Remington Rand believed that the only
way to market computers to the business community was through the development of a language that business people would be
comfortable using. Remington Rand officials were especially committed
to providing a language that resembled English. None of
the attempts to develop a business-oriented language succeeded,
however, and by 1959 Hopper and other members of the U.S. Department
of Defense had persuaded representatives of various companies
of the need to cooperate.
On May 28 and 29, 1959, a conference sponsored by the Department
of Defense was held at the Pentagon to discuss the problem of
establishing a common language for the adaptation of electronic
computers for data processing. As a result, the first distribution of
COBOL was accomplished on December 17, 1959. Although many
people were involved in the development of COBOL, Hopper played
a particularly important role. She not only found solutions to technical
problems but also succeeded in selling the concept of a common
language from an administrative and managerial point of view. Hopper
recognized that while the companies involved in the commercial
development of computers were in competition with one another, the
use of a common, business-oriented language would contribute to
the growth of the computer industry as a whole, as well as simplify
the training of computer programmers and operators.
Consequences
COBOL was the first compiler developed for business data processing
operations. Its development simplified the training required
for computer users in business applications and demonstrated that
computers could be practical tools in government and industry as
well as in science. Prior to the development of COBOL, electronic
computers had been characterized as expensive, oversized adding
machines that were adequate for performing time-consuming mathematics
but lacked the flexibility that business people required.
In addition, the development of COBOL freed programmers not
only from the need to know machine code but also from the need to
understand the physical functioning of the computers they were using.
Programming languages could be written that were both machine-
independent and almost universally convertible from one
computer to another.Finally, because Hopper and the other committee members worked
under the auspices of the Department of Defense, the software
was not copyrighted, and in a short period of time COBOL became
widely available to anyone who wanted to use it. It diffused rapidly
throughout the industry and contributed to the widespread adaptation
of computers for use in countless settings.
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